Bis(dibenzylideneacetone)palladium (0)
Bis(dibenzylideneacetone)palladium
CAS: 32005-36-0
Molecular Formula: C34H20O2Pd
Bis(dibenzylideneacetone)palladium (0) - Names and Identifiers
| Name | Bis(dibenzylideneacetone)palladium |
| Synonyms | PD(DBA)2 Bis(dibenzylideneacetone)palladium BIS(DIBENZYLIDENEACETONE)PALLADIUM Bis(dibenzylideneacetone)palladium(0) BIS(DIBENZYLIDENEACETONE)PALLADIUM(O) BIS(DIBENZYLIDENEACETONE) PALLADIUM(0) Bis(dibenzylideneacetone)palladium (0) Bis(dibenzylideneacetone) palladium(0) PALLADIUM(0) BIS(DIBENZYLIDENEACETONE) PALLADIUM (0) BIS(DIBENZYLIDENEACETONE) SALT Bis(dibenzylideneacetone)palladium(0) Pd(dba)2Pd2(dba)3ba Bis(dibenzylideneacetone)palladium(0) Pd(dba)2Pd2(dba)3dba |
| CAS | 32005-36-0 |
| EINECS | 608-691-6 |
| InChI | InChI=1/2C17H14O.Pd/c2*18-17(13-11-15-7-3-1-4-8-15)14-12-16-9-5-2-6-10-16;/h2*1-14H;/b2*13-11+,14-12+ |
| InChIKey | WTAPZWXVSZMMDG-JZOPPWQGSA-N |
Bis(dibenzylideneacetone)palladium (0) - Physico-chemical Properties
| Molecular Formula | C34H20O2Pd |
| Molar Mass | 566.95 |
| Melting Point | 150°C |
| Boling Point | 400.7°C at 760 mmHg |
| Flash Point | 176.2°C |
| Water Solubility | insoluble |
| Solubility | Chloroform (Slightly) |
| Vapor Presure | 1.25E-06mmHg at 25°C |
| Appearance | Purple brown powder |
| Color | Red-brown to black |
| Storage Condition | under inert gas (nitrogen or Argon) at 2–8 °C |
| Sensitive | Air & Moisture Sensitive |
| MDL | MFCD00051942 |
| Physical and Chemical Properties | Melting point 150°C. Soluble in water. |
| Use | Hydrogenation, isomerization, carbonylation, oxidation, carbon-carbon bond formation reaction. Used in the synthesis of allyl-substituted cyclopentenes. Homologous catalyst. Catalytic alkylation of allyl acetate under mild conditions. Used as a ligand for cyclizing thiourea in the aerobic oxidation reaction of the oxidation of alcohols to aldehydes and ketones. |
Bis(dibenzylideneacetone)palladium (0) - Risk and Safety
| Hazard Symbols | Xi - Irritant |
| Risk Codes | 36/38 - Irritating to eyes and skin. |
| Safety Description | S22 - Do not breathe dust. S24/25 - Avoid contact with skin and eyes. S37/39 - Wear suitable gloves and eye/face protection S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. |
| WGK Germany | 3 |
| TSCA | No |
| HS Code | 28439000 |
Bis(dibenzylideneacetone)palladium (0) - Introduction
Insoluble in water, slightly soluble in dichloromethane, chloroform and benzene.
Last Update：2022-10-16 17:24:34
Bis(dibenzylideneacetone)palladium (0) - Reference Information
| Use | Bis (dibenzylidene acetone) palladium is a compound used as a potentiometer membrane sensor component to selectively determine the presence of thiocyanate in the urine of smokers. Bis (dibenzylidene acetone) palladium is also used as one of the homogeneous catalysts for the synthesis of tricyclopentadiene from dicyclopentadiene. As a catalyst, used in coupling reactions of Suzuki, Kumada, Negishi, etc. |
Last Update：2024-04-09 20:49:11
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